UNIVERSITAS AIRLANGGA



Detail Article

Jurnal Penelitian Medika Eksakta

ISSN 1411-6626

Vol. 8 / No. 2 / Published : 2009-08

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Original Article :

Making the coated wire la3+ ion selective electrode with arboxymethoxy tertierbuthyl calix[n] arene compound

Author :

  1. Muji Harsini*1
  2. Hamami*2

Abstract :

ABSTRACT Preparation and characterization of coated wire La3+ selective electrode has studied in this research. The aim of this research is to look for analysis method of lanthanum using coated wire La3+ ion selective electrode with carboxymethoxy tertierbuthyl calix[n] arene compound as ionophore with 4, 6, and 8 condensation degree. Construction of coated wire ISE-La3+ started with preparation of the membrane from mixture polyvinyl chloride (PVC), nitrophenyl octhyl ether (NPOE), potassium tetrakis chlorophenyl borate (KTCPB) and calyx[n] arene and solven tetrahydrufunan (THF). Electrode body made for platinum wire. End point platinum wire immersed in membrane. Result of research show that condensation degree influential to potential response. Carboxymethoxy tertierbuthyl calix[6] arene compound give potential response is best to La3+ ion with membrane composition 45 mg of PVC, 90 mg of NPOE, 10 mg of KTCPB and 5 mg of carboxymethoxy tertierbuthyl calix[6] arene. Characteristic of this electrode was 19.588 mV/decade, 10-7- 10-1 M, 5.807. 10-8 M respectively to Nernst factor, range concentration and detection limit. Accuracy, and precision in this method was 102,8% and 0,35 – 5, 5% coefficients of variance respectively

Keyword :

calix[n]arene, La3+ ion selective electrode, coated wire,


References :





Archive Article

Cover Media Content

Volume : 8 / No. : 2 / Pub. : 2009-08
  1. The Effect Of Antimalarial Active Isolate From Arthocarpus Champeden On Plasmodium Falciparum Infected Erythrocyte
  2. Identification Of Morphology And Protein Profile Of Sarcoptes Scabiei Mites On Goat And Rabbit
  3. Isolation, Identification And Purification Of Protein Human Menopause Gonadotropin (hmg) From Women Menopause For Follicle Growth And In Vitro Maturation In Dairy Cattle
  4. The Role Of Daun Wungu Ethanol Extracts For Mammary Gland Atrophy Inhibition In Ovariectomized Mice
  5. Making The Coated Wire La3+ Ion Selective Electrode With Arboxymethoxy Tertierbuthyl Calix[n] Arene Compound
  6. Mini Ipal Making For Domestic Detergent Wastewater
  7. Risk Factors Of Communication Of Malaria In Areas Divided By Administrative Boundaries
  8. Cadmium Concentration, Protein And Organoleptic Of Bivalves And Vinegar Soaking

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